A Rice University professorâ€™s method to â€śupconvertâ€ť light could make solar cells more efficient and disease-targeting nanoparticles more effective. Experiments led by Gururaj Naik, an assistant professor of electrical and computer engineering, combined plasmonic metals and semiconducting quantum wells to boost the frequency of light, changing its color. In a nanoscale prototype Naik developed as a postdoctoral researcher at Stanford University, custom-designed pylons that were struck by green light produced a higher-energy blue glow.
â€śIâ€™m taking low-energy photons and converting them to high-energy photons,â€ť he said. Efficient upconversion of light could let solar cells turn otherwise-wasted infrared sunlight into electricity or help light-activated nanoparticles treat diseased cells, Naik said. The work appears in the American Chemical Societyâ€™s Nano Letters. The magic happens inside tiny pylons that measure about 100 nanometers across. When excited by a specific wavelength of light, specks of gold on the tips of the pylons convert the light energy into plasmons, waves of energy that slosh rhythmically across the gold surface like ripples on a pond.
Plasmons are short-lived, and when they decay, they give up their energy in one of two ways; they either emit a photon of light or produce heat by transferring their energy to a single electron â€” a â€śhotâ€ť electron. Naikâ€™s work at Stanford was inspired by the groundbreaking work of professors Naomi Halas and Peter Nordlander at Riceâ€™s Laboratory for Nanophotonics, who had shown that exciting plasmonic materials also excited â€śhot carriersâ€ť â€“ electrons and holes â€“ within. (Electron holes are the vacancies created when an electron is excited into a higher state, giving its atom a positive charge.)
â€śPlasmonics is really great at squeezing light on the nanoscale,â€ť said Naik, who joined Riceâ€™s faculty a year ago. â€śBut that always comes at the cost of something. Halas and Nordlander showed you can extract the optical losses in the form of electricity. My idea was to put them back to optical form.â€ť
He designed pylons using alternate layers of gallium nitride and indium gallium nitride that were topped with a thin layer of gold and surrounded by silver. Instead of letting the hot carriers slip away, Naikâ€™s strategy was to direct both hot electrons and hot holes toward the gallium nitride and indium gallium nitride bases that serve as electron-trapping quantum wells. These wells have an inherent bandgap that sequesters electrons and holes until they recombine at sufficient energy to leap the gap and release photons at a higher frequency.
Present-day upconverters used in on-chip communications, photodynamic therapy, security and data storage have efficiencies in the range of 5 to 10 percent, Naik said. Quantum theory offers a maximum 50 percent efficiency (â€śbecause weâ€™re absorbing two photons to emit oneâ€ť) but, he said, 25 percent is a practical goal for his method.